Crosslighting with the sun

A simple technique that works beautifully is to have one flash on a light stand, in this case to the back right of my daughter and have the sun front left, with both light sources directly facing each other with your subject in the middle. The best examples of this type of photography that I'm familiar with can be found at the State of the Nation Blog. Set your exposure so that the Sun lights your subject nicely, then slowly build up your flash until you get the result you want, making sure that your shutterspeed is below your max sync speed on your camera. If that means nothing to you, but you want to know more, drop me a comment and I'll go into more detail in these posts to explain!